Fullerene bisadduct stabilizers: The effect of different addition positions on inhibiting the autocatalytic decomposition of nitrocellulose absorbed nitroglycerin

To explore the effect of different positions and number of pyrrolidine bound to the carbon cage on the stabilization effect of fulleropyrrolidine derivatives to nitrocellulose (NC)/nitroglycerine (NG), we synthesized N-(4-methoxy) phenylpyrrolidine-C₆₀ and four different of bis(N-(4-methoxy) phenylpyrrolidine)-C₆₀ compounds through Prato reaction. Their structures were characterized by UV–vis, ¹H NMR, ¹³C NMR, high-resolution mass spectroscopy, and single-crystal X-ray diffraction. Their stabilization effect to NC/NG were investigated using differential scanning calorimetry, methyl violet, vacuum stabilization effect, weight loss, and accelerating rate calorimeter tests. The results indicated these compounds had excellent stabilization effect to NC/NG. The stabilization effect of the fulleropyrrolidine bisadducts to NC/NG is significantly better than that of fulleropyrrolidine monoadduct and C₆₀. Moreover, the position where pyrrolidine binds to fullerene in fulleropyrrolidine bisadducts is different, and its stabilization effect to NC is also different. The stabilization effect order of different bisadduct isomers to nitrocellulose is as follows: e-edge > trans-2> cis-2> trans-3. Electron paramagnetic resonance (EPR) and FT-IR were used to study the stabilization mechanism of fulleropyrrolidine derivatives to NC/NG. The EPR results also show that fulleropyrrolidine bisadducts with different addition sites have different abilities to absorb nitroxide, and their ability is better than that of the monoadduct and C₆₀, which is consistent with the results of stabilization effect performance test.     

An interface shear damage model of chromium coating/steel substrate under thermal erosion load

The Cr-plated coating inside a gun barrel can effectively improve the barrel's erosion resistance and thus increase the service life.However,due to the cyclic thermal load caused by high-temperature gun-powder,micro-element damage tends to occur within the Cr coating/steel substrate interface,leading to a gradual deterioration in macro-mechanical properties for the material in the related region.In order to mimic this cyclic thermal load and,thereby,study the thermal erosion behavior of the Cr coating on the barrel's inner wall,a laser emitter is utilized in the current study.With the help of in-situ tensile test and finite element simulation results,a shear stress distribution law of the Cr coating/steel substrate and a change law of the interface ultimate shear strength are identified.Studies have shown that the Cr coating/steel substrate interface's ultimate shear strength has a significant weakening effect due to increasing temperature.In this study,the interfacial ultimate shear strength decreases from 2.57 GPa(no erosion)to 1.02 GPa(laser power is 160 W).The data from this experiment is employed to establish a Cr coating/steel substrate interface shear damage model.And this model is used to predict the flaking process of Cr coating by finite element method.The simulation results show that the increase of coating crack spacing and coating thickness will increase the service life of gun barrel.     

基于RTP协议H．264视频流传输QoS保证的研究

提出一个Linux环境下基于RTP/RTCP的H.264视频流传输的方案,在Linux中调用V4L(VideofourLinux)的API函数采集视频流,经X264压缩,RTP/RTCP协议打包进行传输。并通过RTCP的RR(接收方报告)包反馈信息和吞吐量公式来计算近似带宽,以起始帧量化参数start-qp为视频编码的调节参数,由近似带宽来控制视频编码的参数调整,达到控制输出码率的目的,实现对视频传输的QoS(QualityofService)保证。     

自主式车载组合导航系统研究与仿真

考虑到车载组合导航系统运行时间长、地形环境复杂的特点,将零速修正技术与惯导/里程计/气压高度表组合导航系统相结合使用,采用序贯处理和平方根滤波算法,建立了实用的卡尔曼滤波模型。相比基本卡尔曼滤波算法,该方法实现简单,计算量小,抑制了滤波的发散,提高了滤波的精度。最后对组合导航系统进行仿真验证,取得了较为满意的结果。与INS/GPS组合导航系统相比,该系统具有良好的自主性及适应性。     

舰炮武器系统的总体配置方案及关键技术

针对舰炮武器系统在对岸射击中的不足之处,分析了舰炮武器系统对岸射击时对导航系统的需求,对基于导航定位系统的舰炮武器系统的总体配置设计方案和关键技术进行了探讨;给出了系统整体构架及系统工作原理,指出了关键技术如何实现。为舰炮武器系统的设计及提高舰炮武器系统的作战效能提供了理论参考。     

三坐标雷达目标真实高度估计算法研究

在目标跟踪领域,通过三坐标雷达的测量值(斜距、仰角及方位角)来估算目标的真实高度一直是个难点。目前主要有两类处理方法:坐标转换法和等效地球半径法。前者把与雷达天线相关的三坐标测量值转换到大地坐标系统来计算目标高度;后者充分考虑地球曲率以及大气折射的特性,通过增加地球半径来估算目标的高度。最后对上述的两类方法进行总结、比较与分析。     

一种基于SOAP安全的网络中心发布/订阅机制

针对网络中心发布/订阅系统异步、松散耦合和多对多通信等特点,采用了SOAP消息传递机制对信息进行了封装,从而屏蔽了信息的异构性。考虑到信息传输的可靠性,采用XML-Encryption机制构造SOAP消息,为消息交换和数据传输提供一种安全的保证。实际应用表明该系统在网络中心战中有较好的应用前景。     

具有拟周期外力的非自治发展方程的时滞惯性流形与近似惯性流形

研究了一类具有拟周期外力的非自治发展方程,通过延伸相平面将非自治系统转化为自治系统,再证明相应的自治系统的时滞惯性流形的存在性,并在时滞惯性流形的基础上构造了非自治发展方程的近似惯性流形。     

聚硅氧烷先驱体转化制备2D Cf/Si-O-C材料

以二维碳纤维布和廉价的聚硅氧烷为原料,采用先驱体转化工艺制备2D Cf/Si-O-C材料,对其力学性能进行了考察,并与以聚碳硅烷为先驱体制备的2D Cf/SiC材料在价格和性能方面进行了对比。实验表明,2D Cf/Si-O-C材料力学性能较2D Cf/SiC材料有所下降,但成本大大降低。2D Cf/Si-O-C材料弯曲强度达到157.9 MPa,断裂韧性达到8.4MPa.m1/2,剪切强度达到23.4MPa,并且在1400℃下能较好保持材料的力学性能。     

非自伴情形下时滞抛物方程的惯性流形

利用Lyapunov-Perron方法在适当的谱间隙条件和适当小的时滞假设下,证明了一类非自伴算子情形下半线性时滞抛物方程惯性流形的存在性。